The Ivory Coast set up an African Nations Cup final against Zambia after Gervinho's solo goal saw them ease past Mali 1-0 in Libreville.
The Elephants will return to the same venue on Sunday seeking their second title after the Arsenal forward ran from his own half and slotted home.
His side's defence then kept their opponents at bay in the second half to ensure their progression to the final for the third time.
Siaka Tiene delivered a free-kick from the right and Didier Drogba's downward header bounced up and struck the top of the post.
Goalkeeper Soumaila Diakite, beaten to the ball by Drogba for that chance, then misjudged the bounce of the Chelsea striker's free-kick and was fortunate when the ball bounced into his face and around the post.
He was beaten at his near post by Yaya Toure's powerful drive but again saw the ball rebound to safety off the woodwork.
Mali's first chance fell to Cheick Diabate but Jean-Jaques Gosso made a goal-saving challenge and Sambou Yatabare could not convert the rebound.
Salomon Kalou then poked wide after creditably staying on his feet under a challenge in the penalty area, and Drogba scuffed a shot wide after holding off two defenders.
But Gervinho put the Elephants ahead on the stroke of half-time when he tricked his way past Ousmane Berthe on the halfway line, burst unchallenged into the penalty area and finished coolly.
Diabate chanced his arm from distance early in the second period, but keeper Boubacar Barry saved and held onto the ball as he collided with the post.
Barry's efforts were matched by opposite number Diakite, who tipped over Kalou's goalbound effort.
Yatabare shot just over for Mali, his last contribution before he gave way to Garra Dembele.
Toure twice went close and Diakite saved with his feet from Drogba, and Mali did not seriously threaten an equaliser in the closing stages.
Wear official gear of the 2011/12 Champions League winners, Chelsea.
Price: $21.99 Buy at World Soccer ShopBayern Munich will play for Champions League glory on Saturday, May 19. Get your jersey
Price: $79.99 Buy at World Soccer ShopManchester City won their first English league title since 1968 on Sunday. Get in the Gear.
Price: $79.99 Buy at World Soccer ShopChelsea is looking to win their first Champions League title on Saturday, May 19.
Price: $84.99 Buy at World Soccer ShopThe latest in the adidas Predator series will get the job done at your local soccer field.
Price: $219.99 Buy at World Soccer ShopJuventus won the Scudetto with an impressive unbeaten run in Serie A.
Price: $21.99 Buy at World Soccer ShopGet the official Champions League ball from the Munich Final. It's what the players use!
Price: $149.99 Buy at World Soccer ShopDrogba scored in regulation and knocked in the final PK as Chelsea wins Champions League.
Price: $117.44 Buy at World Soccer ShopTop off your Chelsea look with an official Chelsea cap.
Price: $21.99 Buy at World Soccer Shop
Premier League Table
Premier League Fixtures
Premier League Results
EPL Top Scorers
Soccer365's Premier League stats provided by Fox Soccer. Check out the EPL games on the TV Schedule for this week.
Serie A Table
Serie A Results
Serie A Fixtures
Serie A Top Scorers
Soccer365's Serie A stats provided by Fox Soccer. Check out the Serie A games on the TV Schedule for this week.
La Liga Table
La Liga Results
La Liga Fixtures
La Liga Top Scorers
Soccer365's La Liga stats provided by Fox Soccer. Check out the Fox Soccer TV Schedule for this week.
Bundesliga Table
Bundesliga Results
Bundesliga Fixtures
Bundesliga Top Scorers
Soccer365's Bundesliga stats provided by Fox Soccer. Check out the Fox Soccer TV Schedule for this week.
Champions League Table
Champions League Results
Champions League Fixtures
MLS Table
MLS Results
MLS Fixtures
Soccer365's stats provided by Fox Soccer. Check out the Fox Soccer TV Schedule for this week.